Growth of LSMO as a function of oxygen pressure (schematic)

© Giada Franceschi/IAP

Growth of LSMO as a function of oxygen pressure (schematic)

High-quality surface physics studies require well-defined surfaces, usually single crystals. For many materials of interest, single crystals of sufficient size are not available. Pulsed laser deposition (PLD) is the technique of choice to grow epitaxial films of multielement oxides with well-defined stoichiometry and crystallographic structure. However, the growth of these materials is extremely sensitive to the growth parameters: it is not trivial to obtain crystalline, atomically flat films with the desired composition.

Our lab combines PLD with standard surface science techniques (STM, LEED, XPS, LEIS) to investigate and control the growth of multielement oxides from the most fundamental, atomic-scale, level. We explore how different PLD parameters affect the surface atomic structures of the films, and how, in turn, these affect the growth mechanisms.

The gathered knowledge allows us to grow bulk-like films with atomically flat surfaces suited for UHV investigations of surface processes and reactivity. Examples of epitaxial films grown in our lab are: SrTiO3(110), La0.8Sr0.2MnO3 (LSMO) with (110), and (001) orientations, TiO2 anatase, Ti- and Ni-doped Fe2O3(11̅02), and In2O3(111). These films are currently investigated within our group as well as by international collaborators.

  • M. Riva, G. Franceschi, Q. Lu, M. Schmid, B. Yildiz, U. Diebold
    Pushing the detection of cation nonstoichiometry to the limit
    Physical Review Materials 3, 043802 (2019); doi: 10.1103/PhysRevMaterials.3.043802

  • M. Riva, G. Franceschi, M. Schmid, U. Diebold
    Epitaxial growth of complex oxide films: Role of surface reconstructions
    Physical Review Research 1, 033059 (2019); doi: 10.1103/PhysRevResearch.1.033059

  • G. Franceschi, F. Kraushofer, M. Meier, G. S. Parkinson, M. Schmid, U. Diebold, M. Riva
    A model system for photocatalysis: Ti-doped α-Fe2O3(11̅02) single-crystalline films
    Chemistry of Materials 32, 3753 (2020); doi: 10.1021/acs.chemmater.9b04908

  • G. Franceschi, M. Wagner, J. Hofinger, T. Krajňák, M. Schmid, U. Diebold, M. Riva
    Growth of In2O3(111) thin films with optimized surfaces
    Physical Review Materials 3, 103403 (2019); doi: 10.1103/PhysRevMaterials.3.103403