Catalysts in Multi-states

18. November 2021

Catalysts in Multi-states

A surprising discovery: A catalyst seems to contradict usual laws and can exhibit completely different activity states at the same time.

Image of a surface created with a scanning photon microscope

A research team of our Institute has observed a highly unusual behavior when studying catalytic hydrogen oxidation on rhodium: The surface of a rhodium foil can be highly chemically active in some surface regions, while in others, only a few micrometers away, it is completely inactive, and still in others oscillations between the active and inactive state occur. Such behavior was previously thought to be almost inconceivable. The results, which have now been published in the scientific journal "Nature Communications", show: Catalysis is more complicated than previously thought.

A picture of a surface and an illustration showing individual atoms — Local pattern formation in oscillatory hydrogen oxidation on rhodium: a scanning photoelectron microscope (SPEM) was used to create a chemical map of the species on the catalyst surface (left). Spectroscopic data (XPS) of the surface coverage (right) enable to develop atomic models of the associated surface activity states (middle).

The research team: H. Grönbeck, M. Stöger-Pollach, A.Steiger-Thirsfeld, L. Gregoratti, M. Amati, P. Winkler, J. Zeininger, M. Raab, Y. Suchorski, G. Rupprechter — The international research team.

TU Press Release: https://www.tuwien.at/en/tu-wien/news/news-articles/news/katalysatoren-gleichzeitig-vergiftet-und-sehr-lebendig, opens an external URL in a new window

CHEMIE.DE: https://www.chemie.de/news/1173573/katalysatoren-gleichzeitig-vergiftet-und-sehr-lebendig.html, opens an external URL in a new window

Original publication

P. Winkler et al., Coexisting multi-states in catalytic hydrogen oxidation on rhodium, Nature Communications 12, 6517 (2021)., opens an external URL in a new window

Research funded by the Austrian Science Fund (FWF) within Project „Spatial-temporal phenomena on surface structure libraries“.

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Catalysts in Multi-states