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27. November 2025

New Perspective Proposes the harnessing structural evolution of MOF electrocatalyst

A new Communications Chemistry Perspective by Dr. Zheao Huang and Prof. Dominik Eder argues that the perceived instability of metal–organic frameworks (MOFs) should be viewed as a design advantage rather than a flaw.

Instead of treating MOFs as static solids, the authors emphasize that dynamic structural evolution, including changes in coordination, defect formation and the generation of open metal sites, often produces the true catalytic species under operating conditions.

They call for closer integration of operando spectroscopy, high-resolution microscopy and computational modelling to capture and interpret these transient transformations. By embracing controlled evolution rather than absolute stability, the authors outline a new conceptual direction for developing MOF electrocatalysts that can adapt and improve during reaction, offering a realistic roadmap for more effective catalyst design.

Original publication

Harnessing the structural evolution of metal–organic frameworks under electrocatalytic conditions. Communications Chemistryhttps://doi.org/10.1038/s42004-025-01747-0, opens an external URL in a new window

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